Most adsorbent materials used for preconcentrating and thermally desorbing volatile and semi-volatile organic compounds (S/VOCs) in portable or “micro” gas chromatographic (GC/µGC) instruments preferentially capture non-polar or moderately polar compounds relative to more polar compounds. Here, we explore the use of a known trigonal-tripyramidal room-temperature ionic liquid (RTIL) as a surface modifier for the graphitized carbons, Carbopack B (C-B) and Carbopack X (C-X), with the goal of…